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Zhongyi Liu,Shouchang Liu,Zhongjun Li

Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene

Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene

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  • More about Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene

This book provides a comprehensive overview of catalytic technologies for selective hydrogenation of benzene to cyclohexene, discussing reaction mechanisms,objective laws,and scientific significance. It is aimed at a broad audience, including professionals, students, and practitioners.

Format: Paperback / softback
Length: 347 pages
Publication date: 12 September 2021
Publisher: Springer Verlag, Singapore


This comprehensive book delves into the realm of catalytic technologies for the selective hydrogenation of benzene to cyclohexene, a pivotal process in the production of cyclohexanone, bulk chemicals, and high-value fine chemicals. With a focus on achieving selective hydrogenation to prepare cyclohexene and its downstream products, the book explores the underlying objective laws, reaction mechanisms, and scientific significance based on extensive experimental data, analysis, and characterization results. Spanning its breadth, this text will captivate a wide readership, including professionals working at universities and scientific research institutes, senior undergraduates, master's and doctoral graduate students, as well as practitioners in the industry.

The selective hydrogenation of benzene to cyclohexene is a crucial process in the chemical industry, as it is used to produce a variety of important products. Catalytic technologies have played a significant role in improving the efficiency and selectivity of this reaction, leading to the development of more sustainable and cost-effective processes.

One of the key challenges in selective hydrogenation is achieving high selectivity, which means that only the desired cyclohexene product is produced while minimizing the formation of other byproducts. Catalysts have been developed that can selectively hydrogenate benzene to cyclohexene, with a selectivity of up to 99% or higher. These catalysts are typically based on noble metal compounds, such as platinum, palladium, and rhodium, which have high activity and selectivity towards the desired reaction.

Another challenge in selective hydrogenation is the reaction mechanism. The reaction involves the hydrogenation of benzene to form cyclohexene, followed by the subsequent dehydrogenation of cyclohexene to form cyclohexanone. The reaction mechanism is complex and involves multiple steps, which can be difficult to understand and control. Catalysts have been developed that can promote specific reaction pathways, leading to more efficient and selective hydrogenation.

The selective hydrogenation of benzene to cyclohexene has significant economic and environmental implications. The production of cyclohexanone is used in the production of a wide range of products, including pharmaceuticals, pesticides, and plastics. By using selective hydrogenation, it is possible to reduce the formation of byproducts and improve the overall efficiency of the process. This can lead to reduced energy consumption, lower greenhouse gas emissions, and improved environmental sustainability.

In addition to its economic and environmental benefits, selective hydrogenation of benzene to cyclohexene has significant scientific significance. The reaction mechanism and the development of catalysts have provided insights into the behavior of metals and their interactions with organic compounds. This knowledge has been used to develop new catalysts and improve the performance of existing catalysts, leading to further advancements in the chemical industry.

Overall, the selective hydrogenation of benzene to cyclohexene is a complex process that requires careful consideration of the reaction mechanism, catalyst development, and economic and environmental factors. Catalytic technologies have played a significant role in improving the efficiency and selectivity of this reaction, leading to the development of more sustainable and cost-effective processes. The continued development of catalytic technologies will play an important role in meeting the growing demand for chemical products and improving the environmental sustainability of the chemical industry.

Weight: 557g
Dimension: 235 x 155 (mm)
ISBN-13: 9789811564130
Edition number: 1st ed. 2020

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