Metal-Ligand Co-operativity: Catalysis and the Pincer-Metal Platform

This book provides an overview of recent developments in metal-ligand cooperativity, focusing on pincer architectures, which have significant implications for organometallic chemistry and catalyst development. Co-operative ligands, which participate in bond making and breaking, offer new avenues for accessing robust metal complexes with unusual reactivity patterns.

Format: Paperback / softback
Length: 451 pages
Publication date: 31 March 2022
Publisher: Springer Nature Switzerland AG

This comprehensive book serves as a valuable resource for researchers in the fields of organic chemistry, organometallic chemistry, and homogeneous catalysis. It provides a comprehensive overview of significant recent developments in the area of metal-ligand cooperativity, with a particular focus on pincer architectures. The diverse contributions showcased in this book emphasize the profound impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development.

Understanding and precisely controlling the various elementary reactions that comprise a catalytic cycle is crucial for developing efficient and selective catalytic transformations. Cooperative ligands, which actively participate in bond-making and bond-breaking processes alongside the metal they support, unlock new avenues in this field.

In particular, the use of pincer ligand designs, wherein coordinating arms flank a weak or reactive metal-ligand bond, has proven to be a versatile strategy for accessing robust metal complexes that exhibit unique and selective reactivity patterns. By leveraging the cooperative nature of these ligands, researchers can design and develop catalysts that exhibit exceptional performance in various chemical reactions, including organic synthesis, catalysis, and materials science.

Overall, this book offers a deep understanding of metal-ligand cooperativity and its applications in organometallic chemistry and catalyst development. It serves as a valuable reference for both established researchers and emerging scholars in these fields.

Weight: 706g
Dimension: 235 x 155 (mm)
ISBN-13: 9783030689186
Edition number: 1st ed. 2021