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Physicochemical Aspects of Metal-Organic Frameworks: A New Class of Coordinative Materials
Physicochemical Aspects of Metal-Organic Frameworks: A New Class of Coordinative Materials
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This book provides a detailed and comprehensive look at metal–organic frameworks (MOFs), a new class of materials with broad application potential, covering their classification, synthesis, functionalization, and diverse applications in energy storage, environmental remediation, drug delivery, biosensing, and tissue engineering. It features chapters on designing novel MOF structures and theoretical calculations.
Format: Hardback
Length: 343 pages
Publication date: 04 March 2023
Publisher: Springer International Publishing AG
This book offers a thorough and in-depth exploration of metal-organic frameworks (MOFs), a relatively new class of materials with a wide range of potential applications. The initial chapters provide a foundational understanding of MOFs, including their classification, synthesis, functionalization methods, and various physiochemical characteristics such as structural morphology and coordination chemistry. The subsequent chapters cover a diverse range of applications, spanning from energy storage and environmental remediation to drug delivery, biosensing, and tissue engineering. Special attention is given to chapters dedicated to the design of novel MOF structures, as well as theoretical calculations utilizing density functional theory and machine learning techniques. This book is intended for a broad audience of academic and industrial researchers who are interested in gaining a deep understanding of the latest MOF structure-function relationships and their practical applications in coordinated engineering endeavors.
Introduction:
Metal-organic frameworks (MOFs) are a class of materials that have gained significant attention in recent years due to their unique properties and vast potential applications. MOFs are composed of metal ions or clusters linked together by organic ligands, resulting in highly ordered and porous structures with a large surface area. These materials exhibit excellent chemical stability, thermal conductivity, and gas adsorption capabilities, making them suitable for various fields such as energy storage, catalysis, drug delivery, and environmental remediation.
Chapter 1:
In this chapter, the authors provide a comprehensive introduction to MOFs, including their classification, synthesis, and functionalization approaches. The classification of MOFs is discussed in detail, with a focus on the different types of metal centers, organic ligands, and structural motifs that can be used to create MOFs. The synthesis of MOFs is also covered, including the methods used to prepare MOFs, such as sol-gel synthesis, template-directed synthesis, and hydrothermal synthesis. Additionally, the authors discuss the functionalization of MOFs, which involves modifying their properties to suit specific applications.
Chapter 2:
In this chapter, the authors explore the structural morphology of MOFs, which refers to their physical properties and microstructure. The authors discuss the various methods used to characterize MOFs, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). They also discuss the factors that influence the structural morphology of MOFs, such as the size and shape of the metal centers, the nature of the organic ligands, and the synthesis conditions.
Chapter 3:
In this chapter, the authors discuss the coordination chemistry of MOFs, which refers to the interactions between the metal centers and the organic ligands. The authors discuss the different types of coordination complexes that can be formed in MOFs, such as chelates, bidentates, and polydentates. They also discuss the factors that influence the coordination chemistry of MOFs, such as the pH, temperature, and the presence of other molecules.
Chapter 4:
In this chapter, the authors explore the various applications of MOFs in different fields. The applications of MOFs in energy storage are discussed in detail, with a focus on their use as battery materials, hydrogen storage materials, and supercapacitors. The applications of MOFs in catalysis are also covered, with a focus on their use as catalysts for organic reactions, such as the synthesis of pharmaceuticals and polymers. Additionally, the authors discuss the applications of MOFs in drug delivery, biosensing, and tissue engineering.
Chapter 5:
In this chapter, the authors discuss the design of novel MOF structures. The authors discuss the use of computational methods, such as density functional theory (DFT) and machine learning techniques, to design MOF structures. They also discuss the factors that influence the design of MOF structures, such as the size and shape of the metal centers, the nature of the organic ligands, and the desired properties of the final MOF.
Chapter 6:
In this chapter, the authors discuss the theoretical calculations of MOFs using DFT and machine learning techniques. The authors discuss the methods used to calculate the electronic structure of MOFs, the energy levels of the metal centers, and the interactions between the metal centers and the organic ligands. They also discuss the limitations of these methods and the potential for further development.
Conclusion:
In conclusion, this book offers a comprehensive and in-depth exploration of MOFs, including their classification, synthesis, functionalization approaches, structural morphology, coordination chemistry, and various applications. The authors have done an excellent job of presenting the material in a clear and concise manner, making it accessible to a broad audience of academic and industrial researchers. The book is a valuable resource for those interested in gaining a deeper understanding of the latest MOF structure-function relationships and their practical applications in coordinated engineering endeavors.
Weight: 699g
Dimension: 235 x 155 (mm)
ISBN-13: 9783031186745
Edition number: 1st ed. 2023
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