The Handbook of Polyhydroxyalkanoates: Postsynthetic Treatment, Processing and Application

The third volume of the Handbook of Polyhydroxyalkanoates (PHA) focuses on the production of functionalized PHA bio-polyesters, post-synthetic modification, processing, and additive manufacturing, development and properties of PHA-based composites and blends, market potential, bulk- and niche applications, and the fate and use of spent PHA items. It is aimed at graduate students and professionals in polymer science, chemical engineering, and bioprocessing.

Format: Paperback / softback
Length: 410 pages
Publication date: 25 September 2023
Publisher: Taylor & Francis Ltd

The third volume of the Handbook of Polyhydroxyalkanoates (PHA) delves into the realm of producing functionalized PHA bio-polyesters, the post-synthetic modification of PHA, the processing and additive manufacturing of PHA, the development and properties of PHA-based (bio)composites and blends, the market potential of PHA and follow-up materials, diverse bulk- and niche applications of PHA, and the fate and utilization of spent PHA items. Spanning fourteen chapters, this comprehensive handbook provides detailed insights into functionalized PHA and PHA modification, processing, and their diverse applications, including the degradation of spent PHA-based products and the fate of these bio-polyesters during compositing and other disposal strategies. With a focus on graduate students and professionals in the fields of polymer science, chemical engineering, and bioprocessing, this text serves as a valuable resource for advancing knowledge in the field.

Chapter 1: Introduction

The Handbook of Polyhydroxyalkanoates (PHA) serves as a comprehensive reference for the latest advancements in the production, modification, processing, and applications of these environmentally friendly biopolymers. In the third volume, we delve into the intricate details of functionalized PHA bio-polyesters, post-synthetic modification, processing, and additive manufacturing. We also explore the development and properties of PHA-based (bio)composites and blends, as well as the market potential and follow-up materials of PHA.

Chapter 2: Functionalized Polyhydroxyalkanoates

This chapter provides an in-depth exploration of the synthesis and characterization of functionalized PHA bio-polyesters. It covers multistep modifications of isolated biopolyesters, short syntheses of monomer feedstocks, and other innovative approaches to tailor the properties of PHA for specific applications. The chapter also discusses the design of functionalized PHA-based polymeric materials by chemical modification, highlighting the importance of understanding the chemical structure-property relationships in these materials.

Chapter 3: Design of Functionalized Polyhydroxyalkanoates

In this chapter, we discuss the design of functionalized PHA-based polymeric materials by chemical modification. We explore the use of various modifying agents, such as acids, bases, and functional groups, to alter the physicochemical properties of PHA. The chapter also highlights the importance of controlling the molecular weight, molecular weight distribution, and stereochemistry of PHA to achieve desired properties.

Chapter 4: Preparation of Bioactive Oligomers Derived from Microbial PHA and Synthetic Analogues of Natural PHA Oligomers

This chapter focuses on the preparation of bioactive oligomers derived from microbial PHA and synthetic analogues of natural PHA oligomers. It discusses the isolation and purification of PHA oligomers, as well as the synthesis of novel oligomers with specific functional groups and properties. The chapter also explores the potential applications of these bioactive oligomers in various fields, such as medicine, agriculture, and materials science.

Chapter 5: Processing and Thermomechanical Properties of Polyhydroxyalkanoates

This chapter provides a comprehensive review of the processing and thermomechanical properties of PHA. It discusses the various methods used to produce PHA, such as fermentation, extraction, and chemical synthesis. The chapter also explores the influence of processing conditions, such as temperature, pressure, and pH, on the properties of PHA, including its mechanical strength, thermal stability, and biodegradability.

Chapter 6: Advantages of Polyhydroxyalkanoates against Other Bio-Based and Conventional Polymers

In this chapter, we compare the advantages of PHA against other bio-based and conventional polymers. We discuss the unique properties of PHA, such as its biocompatibility, biodegradability, and renewable nature, as well as its potential to replace traditional petroleum-based polymers in various applications. The chapter also highlights the current applications and potential uses of PHA-based polymers, emphasizing innovative products that have been developed in recent years.

Chapter 7: Diverse Bulk- and Niche Applications of Polyhydroxyalkanoates

This chapter explores the diverse bulk- and niche applications of PHA. It discusses the use of PHA in various industries, such as packaging, agriculture, medicine, and textiles. The chapter also highlights the potential of PHA in developing sustainable and eco-friendly solutions for waste management, energy storage, and other environmental challenges.

Chapter 8: Market Potential and Follow-Up Materials of Polyhydroxyalkanoates

This chapter examines the market potential and follow-up materials of PHA. It discusses the current market trends, the demand for PHA-based products, and the challenges faced in the commercialization of PHA. The chapter also highlights the development of new technologies and materials that can enhance the performance and sustainability of PHA-based products.

Chapter 9: Fate and Use of Spent Polyhydroxyalkanoates

This chapter focuses on the fate and use of spent PHA items. It discusses the degradation of PHA-based products, the recycling of PHA, and the potential applications of spent PHA in various fields, such as agriculture, energy production, and waste management. The chapter also highlights the importance of developing sustainable disposal strategies for spent PHA to minimize its environmental impact.

Chapter 10: Conclusion

In conclusion, the third volume of the Handbook of Polyhydroxyalkanoates provides a comprehensive and up-to-date overview of the development and applications of PHA. It covers a wide range of topics, from functionalized PHA bio-polyesters to post-synthetic modification, processing, and additive manufacturing. The handbook is aimed at graduate students and professionals in polymer science, chemical engineering, and bioprocessing, and it serves as a valuable resource for advancing knowledge in this field.

By exploring the latest advancements in PHA research, the handbook aims to contribute to the development of sustainable and eco-friendly solutions for various industries. It highlights the potential of PHA as a renewable and biodegradable alternative to traditional petroleum-based polymers, and it emphasizes the importance of developing innovative products and technologies to enhance the performance and sustainability of PHA-based materials.

As the field of PHA continues to evolve, the handbook will remain an essential resource for researchers, industry professionals, and policymakers interested in advancing the use of PHA in a wide range of applications. We anticipate that future editions of the handbook will continue to provide valuable insights and updates on the latest developments in PHA research and its applications.

Weight: 760g
Dimension: 234 x 156 (mm)
ISBN-13: 9780367541156