The Thermodynamics of Phase and Reaction Equilibria

The Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a solid foundation for understanding abstract concepts and applying them to solve practical problems, with the help of computational software and Mathcad®. It covers phase equilibrium problems with nonideal mixtures and chemical reaction equilibrium problems with multiple reactions.

Format: Hardback
Length: 858 pages
Publication date: 25 June 2021
Publisher: Elsevier Science Publishing Co Inc

The Thermodynamics of Phase and Reaction Equilibria, Second Edition, serves as a robust foundation for comprehending abstract concepts such as partial molar Gibbs energy, fugacity, and activity, and demonstrates their practical application in solving real-world problems through numerous clear examples. With the availability of computational software, students now have the capability to tackle complex and challenging problems from the industrial realm. The second edition of this text includes phase equilibrium problems involving nonideal mixtures with more than two components and chemical reaction equilibrium problems involving multiple reactions. These computations are facilitated using Mathcad®.

Understanding phase and reaction equilibria is crucial in various fields, including chemistry, chemical engineering, and materials science. These equilibria determine the composition and properties of mixtures at equilibrium, and they play a vital role in determining the feasibility and stability of chemical processes. By studying thermodynamics, students gain insights into the driving forces behind these equilibria and how they can be manipulated to achieve desired outcomes.

One of the key concepts in thermodynamics is the concept of phase equilibrium. Phase equilibrium occurs when the concentrations of all species in a mixture are uniform, and the mixture exists in a single phase. This equilibrium is governed by the principles of chemical potential, activity, and entropy. For example, when two or more substances are mixed together, they may form a solid, liquid, or gas phase depending on the temperature and pressure. The phase equilibrium constants, which are determined by the thermodynamic properties of the substances, determine the relative proportions of each phase at equilibrium.

Reaction equilibrium, on the other hand, occurs when the forward and reverse reactions of a chemical process occur at the same rate. This equilibrium is governed by the equilibrium constants for the forward and reverse reactions. The equilibrium constants are determined by the thermodynamic properties of the reactants and products, as well as the reaction conditions. For example, the equilibrium constant for the reaction between hydrogen gas and oxygen gas to form water is very large, indicating that the reaction proceeds rapidly toward equilibrium.

Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a comprehensive and up-to-date introduction to these concepts. The book covers a wide range of topics, including phase diagrams, thermodynamic properties, and the application of phase and reaction equilibria to practical problems. It includes numerous examples and problems to help students understand the concepts and apply them to real-world situations.

One of the strengths of this book is its clear and concise writing style. The authors have a strong understanding of the subject matter and have done an excellent job of explaining complex concepts in a way that is accessible to students with a variety of backgrounds. The book also includes numerous figures and tables to illustrate the concepts and make them more visually appealing.

In addition to its theoretical aspects, Thermodynamics of Phase and Reaction Equilibria, Second Edition, emphasizes the practical applications of these concepts. The book includes numerous examples from the industrial sector, demonstrating how phase and reaction equilibria are used to design and optimize chemical processes. It also discusses the use of computational software, such as Mathcad®, to carry out computations and solve complex problems.

Another notable feature of this book is its emphasis on sustainability and environmental concerns. The authors recognize the importance of reducing greenhouse gas emissions and promoting sustainable practices in the chemical industry. They discuss the role of phase and reaction equilibria in designing environmentally friendly processes and the use of renewable energy sources to power chemical plants.

In conclusion, Thermodynamics of Phase and Reaction Equilibria, Second Edition, is an excellent resource for students studying thermodynamics and chemical engineering. The book provides a solid foundation for understanding abstract concepts such as phase and reaction equilibria and demonstrates their practical application in solving real-world problems. With its clear and concise writing style, numerous examples, and emphasis on practical applications, this book is sure to be a valuable tool for students in these fields. Whether you are a beginner or an advanced student, Thermodynamics of Phase and Reaction Equilibria, Second Edition, will help you deepen your understanding of these important concepts and prepare you for success in your academic and professional endeavors.

Weight: 1000g
Dimension: 235 x 191 (mm)
ISBN-13: 9780128205303
Edition number: 2 ed