Mixed-Valence Systems - Fundamentals, Synthesis, Electron Transfer, and Applications

Mixed-Valence Systems is a comprehensive overview of advanced development in mixed-valence chemistry, covering design, synthesis, electron transfer, and applications. It discusses the recent advances in mixed-valence chemistry, such as new systems, transition of mixed valency, and electron transfer related to molecular electronics.

Format: Hardback
Length: 512 pages
Publication date: 12 April 2023
Publisher: Wiley-VCH Verlag GmbH

Mixed-Valence Systems: A Comprehensive Overview of Advanced Development in Mixed-Valence Chemistry

Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications delves into the intricate realm of mixed-valence chemistry, encompassing a wide range of topics related to the theory and experimental outcomes of these systems. This comprehensive text covers the design, synthesis, and applications of mixed-valence compounds featuring inorganic, organometallic, and organic redox-active centers. Furthermore, it explores the recent advancements in mixed-valence chemistry, encompassing the development of novel mixed-valence systems, the exploration of transition of mixed valency, a deeper understanding of the spectral properties of intervalence charge transfer, and the controllable electron transfer associated with molecular electronics.

In this comprehensive guide, readers will find in-depth coverage of key topics such as:

Characterization and Evaluation of Mixed-Valence Systems: This section explores the methods employed to characterize and evaluate mixed-valence systems, including electron paramagnetic resonance spectroscopy and electrochemical techniques.

Optical Analysis: This section delves into the important issues in mixed-valence chemistry, including the transition of mixed valency from localized to delocalized states, as well as the control of electron transfer through solvent manipulation.

Theoretical Background: This section provides a theoretical foundation for understanding mixed-valence systems, covering topics such as potential energy surfaces, the classical two-state model, and the quantum description of potential energy surfaces.

Reorganization Energies, Electronic Coupling Matrix Elements, and Transition Moments: This section explores the reorganization energies, electronic coupling matrix elements, and transition moments associated with mixed-valence systems. It also discusses the generalized Mulliken–Hush theory and the analysis of the band shape of intervalence charge transfer.

Strengthening the Relationship between Mixed-Valence Electron Transfer and Molecular Electronics: This section highlights the interplay between mixed-valence electron transfer and molecular electronics, emphasizing the importance of these processes in various applications such as optoelectronics.

Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications is an invaluable resource for researchers and professionals engaged in the fields of electron transfer, molecular electronics, and optoelectronics. By providing a comprehensive and up-to-date overview of this dynamic field, this text equips readers with the knowledge and tools necessary to advance their understanding and contribute to the ongoing advancements in mixed-valence chemistry.

Weight: 1116g
Dimension: 251 x 176 x 30 (mm)
ISBN-13: 9783527349807