Perspectives on Structure and Mechanism in Organic Chemistry

Perspectives on Structure and Mechanism in Organic Chemistry is a textbook written for advanced undergraduates and beginning graduate students that uses complementary conceptual models to give new perspectives on the structures and reactions of organic compounds. It covers fundamental concepts of organic chemistry, density functional theory, quantum theory of atoms in molecules, Marcus Theory, and molecular simulations, as well as asymmetric induction in nucleophilic additions to carbonyl compounds and dynamic effects on reaction pathways. The text is an excellent learning resource for students of organic chemistry, medicine, and biochemistry and is ideal as a primary text for courses entitled Advanced Organic Chemistry at the upper undergraduate and graduate levels.

Format: Hardback
Length: 864 pages
Publication date: 01 June 2023
Publisher: John Wiley & Sons Inc

"Beyond the Basics" is a comprehensive physical organic chemistry textbook designed for advanced undergraduates and beginning graduate students. Authored by experienced educators, this textbook offers fresh insights into the structures and reactions of organic compounds, aiming to inspire students to think beyond the traditional models taught in introductory organic chemistry courses.

The 3rd Edition of "Beyond the Basics" has been extensively revised and updated to reflect the latest developments in the field. The author has reorganized the content to introduce computational chemistry earlier and create a more seamless flow of topics, starting from substitution reactions to elimination reactions and finally to addition reactions. Approximately 20% of the 438 problems have been either replaced or updated, and comprehensive answers are provided in the companion solutions manual.

In addition to its technical content, "Beyond the Basics" emphasizes the human aspect of science. The text incorporates the names of prominent investigators throughout, providing students with real-world examples and references to original literature for further exploration. Sample topics covered in the textbook include fundamental concepts of organic chemistry, such as atoms and molecules, heats of formation and reaction, bonding models, and double bonds.

Density functional theory, quantum theory of atoms in molecules, Marcus Theory, and molecular simulations are also discussed in detail. Asymmetric induction in nucleophilic additions to carbonyl compounds and dynamic effects on reaction pathways are explored, along with reactive intermediates, including reaction coordinate diagrams, radicals, carbenes, and other reactive species.

By offering a comprehensive and interdisciplinary approach, "Beyond the Basics" equips students with the tools they need to develop new ideas and advance their understanding of organic chemistry. Whether they are aspiring researchers or seeking a deeper appreciation of the field, this textbook is an invaluable resource for anyone interested in exploring the complexities of structure and mechanism in organic chemistry.

Weight: 2284g
Dimension: 223 x 287 x 55 (mm)
ISBN-13: 9781119808619
Edition number: 3 ed